This article has been reviewed according to Science X's editorial process and policies. Editors have highlighted the following attributes while ensuring the content's credibility: Cornell physicists have discovered that minimizing disorder, not varying electron count, is the key factor for controlling superconductivity in the unique material iron selenide (FeSe), a new insight for understanding high-temperature superconductors. Using a new technique to control this iron-based superconductor, researchers in Kyle Shen's lab have found that iron selenide's superconducting "dome"—the curve tracing how superconductivity strengthens and then weakens as the properties are tuned—is more closely linked to resistance caused by imperfections in its crystal lattice than to the number of electrons flowing through the crystal.
Iron selenide could be fundamentally different from other high-temperature (or unconventional) superconductors, the finding suggests. "We found that in this material, that dome is driven by factors much different than what you see normally," said postdoctoral researcher Paul Malinowski, a former Klarman Postdoctoral Fellow in the College of Arts and Sciences (A&S). "It's not driven by how many electrons you're adding in, but rather, it's driven by the obstacles the electrons are hitting—how perfect or imperfect is the crystal lattice?" The study "What controls the superconducting dome of electron-doped FeSe?" was published in the Proceedings of the National Academy of Sciences on Aug. 20, with Malinowski as first author.
"It's an important new result that could give a lot of insight into high-temperature superconductivity," said Shen, the James A. Weeks Professor of Physical Sciences and Stephen H. Weiss Presidential Fellow (A&S) and director of the Laboratory of Atomic and Solid State Physics, corresponding author of the study.
"The key is the ability to precisely control the doping in the fashion Paul has been able to accomplish." For years, researchers have tried and failed to understand the dome of iron selenide, Shen said, because the material's chemistry resisted conventional doping methods, so Malinowski and colleagues had to invent a new way to study it. The standard way to add electrons to a material system is to grow a new compound that has more electrons in it, Malinowski said. "But that means every time you want to change the number of electrons, you have to grow a completely new material.
Not only is that a lot of work; you're also changing the material every time so other things might be changing that you don't know and can't control." In their new approach, Malinowski and colleagues synthesized samples using a technique called molecular beam epitaxy (MBE) and added electrons by spraying them on the surface of the material in a process called alkali surface deposition. The material properties were then probed using a combination of in situ electrical transport and angle-resolved photoemission spectroscopy (ARPES). This was done in ultrahigh vacuum, using the alkali metal cesium.
MBE and alkali deposition are both techniques used elsewhere, but the Shen lab, which has expertise in synthesizing thin films, was uniquely positioned to combine the synthesis with electrical and spectroscopic probes, Malinowski said, without removing or regrowing the sample. "The novel thing here is we can do it all at once in a very comprehensive way," he said. "That turned out to be essential for figuring out what's going on." Discover the latest in science, tech, and space with over 100,000 subscribers who rely on Phys.org for daily insights. d research that matter—daily or weekly.
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