This article has been reviewed according to Science X's editorial process and policies. Editors have highlighted the following attributes while ensuring the content's credibility: Adhesives are essential in electronics, vehicles and other products, but they can hinder repair and recycling when bonded parts are difficult to separate cleanly. A research team led by The University of Osaka has developed a prototype light-responsive adhesive that can be selectively detached from an illuminated surface without leaving observable residue.
The adhesive film can then be rebonded by heating and reused after a second ultraviolet wavelength helps reset its molecular interactions. This study was published in Matter & Light. Conventional photoresponsive adhesives release a bond by weakening or chemically changing the adhesive layer itself.
That approach can leave residue on a substrate. Other systems achieve cleaner separation through irreversible light-driven reactions, but the adhesive is then difficult to reuse. The team instead aimed to control only the adhesive-substrate interface while keeping the bulk adhesive intact.
The researchers designed a polymer adhesive with reversible host-guest crosslinks between stilbene and triacetylated beta-cyclodextrin. Inspired by photoresponsive actuators, light-driven changes in these crosslinks alter local surface mechanics, creating "interfacial switching." Under UV-A light (365 nm), stilbene photoisomerization weakens host-guest association near the illuminated surface. In the optimized material, peel strength fell by about 45%, allowing selective peeling without observable adhesive residue.
Similar switching was demonstrated with PET paired with glass, carbon-fiber-reinforced plastic, Nylon 66 and aluminum. UV-C light (254 nm) restored host-guest association and adhesion. The light-controlled response was retained through 15 peeling cycles; samples were rebonded by heating without solvent processing.
Atomic force microscopy confirmed reversible changes in surface stiffness and adhesion. By switching adhesion at the interface instead of damaging the adhesive bulk, this strategy could ease disassembly, repair and recycling of electronic, automotive and semiconductor components. It also offers a design principle for dynamic polymer interfaces and circular manufacturing.
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